Task Progress:
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At the completion of an NSBRI (National Space Biomedical Research Institute) grant to develop an Oxygen Concentrator, Dr. Ritter and his team incorporated a new PSA module with a redesigned compressor into a prototype oxygen concentrator, and these systems have been delivered to NASA’s Marshall Space Flight Center (MSFC) and Glenn Research Center (GRC) in 2014. Long-term testing and review of performance data at MSFC will indicate any degradation of the adsorbent materials due to trace contaminant poisoning. The prototype delivered to GRC was tested in the Exploration Atmospheres Lab.
The Exploration Atmospheres Lab includes the test chamber, a vacuum exhaust system, a gas supply rack, chiller, power supplies, and data acquisition system. The test chamber is a 60 cm x 60 cm x 60 cm vacuum chamber with a cold plate at the floor level. A chiller is used to provide temperature-conditioned water to the cold plate in the bottom of the chamber. This is used primarily for heat rejection to maintain the chamber temperature at near-ambient conditions. Saturated salts are used to control the initial humidity in the chamber. A vacuum system is used to evacuate the chamber so it can be filled with the desired gas mixture. If the concentrator cannot withstand a hard vacuum, the chamber is partially evacuated and filled with the desired gas mixture repeatedly to obtain the desired ambient oxygen concentration and total pressure.
The chamber is filled from the bottle rack, which contains different O2-N2 blends of 21% O2, 30% O2, and 34% O2. In addition, a combustion products ‘air’ blend is present that contains 1% CO2 and 55 ppm of CO. Additional bottles of 95% O2 and 100% N2 are used to calibrate and purge the oxygen sensor before and after each test, respectively. The oxygen concentrator is placed in the test chamber, draws in the ambient atmosphere from the chamber, and separates the gases to a waste stream that is predominantly nitrogen, and a product stream which is predominantly oxygen. Each of the three flow streams is measured for pressure, flow rate, temperature, humidity, and the oxygen concentration of the product stream is also measured. In addition, the voltage and current draw of the prototype was measured, and CO and CO2 sensors were used in some tests that used a gas mixture with these contaminants present.
At the end of the testing, a report was finished comparing the Ritter PSA Prototype to the Lynntech Electrochemical Prototype we received and tested in 2012. This report serves as our annual report this year. Both prototypes were tested in the same lab, and were judged against the current flight oxygen concentrator requirements. Both prototypes met some of the requirements, but not all of them, since these are prototype units and not high TRL (technology readiness level). The PSA prototype successfully met 12 of 23 requirements, and the electrochemical prototype met 8 of 23 requirements. Based on this evaluation, the PSA technology had a clear technical advantage over the electrochemical technology.
In addition, in 2014, two Phase I SBIRs (Small Business Innovation Research) were awarded pursuing two different technologies (Vacuum Swing Adsorption - VSA, and a different electrochemical design). The TDA, Inc. SBIR Phase I developed an oxygen generator based on a vacuum swing adsorption (VSA) to produce concentrated medical oxygen. They designed and built and evaluated the performance of the sorbent in a breadboard bench-scale prototype. The unit uses ambient vehicle cabin air as the feed and delivers high purity oxygen. TDA's VSA system uses a modified version of the lithium exchanged low silica X zeolite (Li-LSX), a state-of-the-art air separation sorbent extensively used in commercial Portable Oxygen Concentrators (POCs) to enhance the N2 adsorption capacity. The Reactive Innovations SBIR Phase I developed a modular electrochemical subscale concentrator and performed a preliminary design based on the performance of their arrangement of modular separation units. They demonstrated that modular separation units could be manufactured that separated oxygen from exploration atmospheres to produce pure oxygen. The modular separation units were compact, light-weight, and low cost serving both NASA needs and Reactive Innovation’s commercial pursuits.
Lastly, a technology development plan was updated this year, and the Oxygen Concentrator Module (OCM) project has had extensive discussions with Johnson Space Center (JSC) and NASA Headquarters (HQ) personnel regarding synergy with EVA high pressure, high purity oxygen requirements for exploration missions. We also identified oxygen needs for pre-breathing prior to EVA and in the event of a toxic spill or fire.
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Abstracts for Journals and Proceedings
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Erden L, Ebner AD, Nicholson MA, Holland CE, Ritter JA, Trinh D, Shapiro A, Knox JC, Mitchell LA, LeVan MD. "On the Variability and Reproducibility of Equilibrium Adsorption Isotherm Measurements from Different Laboratories." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 343254. https://aiche.confex.com/aiche/2013/webprogram/Paper343254.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Mitchell LA, Giesy TJ, LeVan MD. "Adsorption Equilibrium and Mass Transfer Rates for Argon, Oxygen, and Nitrogen in a Carbon Molecular Sieve." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 328755. https://aiche.confex.com/aiche/2013/webprogram/Paper328755.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Wu F, Ebner AD, Ritter JA. "Hybrid PSA-Distillation Process for Propane/Propylene Separation." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 340879. https://aiche.confex.com/aiche/2013/webprogram/Paper340879.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Hossain MI, Ebner AD, Holland CE, Ritter JA. "Diffusion of N2 and CO2 in 13X Zeolite from Volumetric Frequency Response Measurements Up to 10 Hz." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 340559. https://aiche.confex.com/aiche/2013/webprogram/Paper340559.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Rahman A, Ebner AD, Erden H, Holland C, Ritter JA. "Rapid Cycling of Pure Gases in a Single Bed PSA Apparatus." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 339499. https://aiche.confex.com/aiche/2013/webprogram/Paper339499.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Mohammadi N, Abdollahi A, Nicholson MA, Ebner AD, Holland CE, Ritter JA. "CO2 Capture from Flue Gas by PSA Utilizing a Structured Adsorbent." 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. 2013 AIChE Annual Meeting, San Francisco, California, November 3-8, 2013. Abstract 339352. https://aiche.confex.com/aiche/2013/webprogram/Paper339352.html ; accessed 2/17/21. , Nov-2013
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Abstracts for Journals and Proceedings
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Ritter JA. "Pressure Swing Adsorption: A Ubiquitous Gas Separation Technology." 32nd International Carbon Conference, Pittsburgh, PA, September, 2013. 32nd International Carbon Conference, Pittsburgh, PA, September, 2013. , Sep-2013
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Abstracts for Journals and Proceedings
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Ritter JA, Hossain MI, Ebner AD. "Adsorption and Diffusion of Gases in Microporous Adsorbents Using Volumetric Frequency Response." 246th American Chemical Society (ACS) National Meeting, Indianapolis, IN, September 8-12, 2013. 246th American Chemical Society (ACS) National Meeting, Indianapolis, IN, September 8-12, 2013. , Sep-2013
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Abstracts for Journals and Proceedings
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Ritter JA. "Rapid Pressure Swing Adsorption for CO2 Capture." 2013 NETL CO2 Capture Technology Meeting, Pittsburgh, PA, July 8-11, 2013.
2013 NETL CO2 Capture Technology Meeting, Pittsburgh, PA, July 8-11, 2013. , Jul-2013
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Abstracts for Journals and Proceedings
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Olson SL, Hussey S. "Multipurpose Oxygen Concentrator for Future Exploration Missions." Poster session presentation. 2015 Human Research Program Investigators' Workshop, Galveston, TX, January 13-15, 2015. Poster session presentation. 2015 Human Research Program Investigators' Workshop, Galveston, TX, January 13-15, 2015. , Jan-2015
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Abstracts for Journals and Proceedings
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Gilkey KM, Olson SL, Hussey SW. "Evaluation of Oxygen Concentrator Prototypes for Providing Supplemental Oxygen During Spaceflight." Poster session presentation. 2015 Human Research Program Investigators' Workshop, Galveston, TX, January 13-15, 2015. 2015 Human Research Program Investigators' Workshop, Galveston, TX, January 13-15, 2015. , Jan-2015
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Abstracts for Journals and Proceedings
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Olson SL, Hussey SW, Calaway K. "Development of an Oxygen Concentrator for Future Exploration Missions." 85th Annual Scientific Meeting, Aerospace Medical Association, San Diego, CA, May 10-15, 2014. Aviation, Space, and Environmental Medicine. 2014 Mar;85(3):273. See http://www.ingentaconnect.com/content/asma/asem/2014/00000085/00000003 , Mar-2014
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Abstracts for Journals and Proceedings
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Olson SL, Hussey SW, Calaway K. "Development of an Oxygen Concentrator for Future Exploration Missions." 2014 Human Research Program Investigators' Workshop, Galveston, TX, February 12-13, 2014. 2014 Human Research Program Investigators' Workshop, Galveston, TX, February 12-13, 2014. http://www.hou.usra.edu/meetings/hrp2014/pdf/3013.pdf , Feb-2014
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Articles in Peer-reviewed Journals
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Ebner AD, Mehrotra A, Ritter JA. "Graphical unit block approach for complex PSA cycle scheduling of parallel interacting trains of columns and tanks." Adsorption. 2015 Apr;21(3):229-24. http://dx.doi.org/10.1007/s10450-015-9665-9 , Apr-2015
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